Practice Principle Of Operation (12.3.1) - Chapter 12: Spectroscopic Identification of Organic Compounds
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Principle of Operation

Practice - Principle of Operation - 12.3.1

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Practice Questions

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Question 1 Easy

What is the first step in mass spectrometry?

💡 Hint: Think about how we convert a molecule into ions.

Question 2 Easy

What does the molecular ion peak represent?

💡 Hint: Consider what happens to the molecule during ionization.

4 more questions available

Interactive Quizzes

Quick quizzes to reinforce your learning

Question 1

What does the molecular ion peak (M⁺) represent in a mass spectrum?

Fragment of the molecule
Molecular mass of the intact molecule
Base peak

💡 Hint: Think about what doesn’t change in the molecule during ionization.

Question 2

True or False: The base peak represents the molecular ion.

True
False

💡 Hint: Recall which peak is the highest in the spectrum.

2 more questions available

Challenge Problems

Push your limits with advanced challenges

Challenge 1 Hard

You have a compound with a mass spectrum showing an M⁺ peak at 58 m/z and a base peak at 29 m/z. Identify possible functional groups present in the compound.

💡 Hint: Look closely at common fragment patterns when analyzing the m/z ratios.

Challenge 2 Hard

Explain how you would estimate the number of carbon atoms in a compound using the ratio of the M⁺ and M+1 peaks.

💡 Hint: Think about how the presence of 13C isotopes influences the M+1 peak's intensity.

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