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The d- and f-block elements, comprising transition metals and inner transition metals, are characterized by their unique electronic configurations, variable oxidation states, and metallic properties. Comprised of the elements from Groups 3-12 (d-block) and the lanthanides and actinides (f-block), these metals demonstrate significant trends in their physical and chemical behaviors, including high tensile strength, conductivity, and catalytic activity. The chapter further explores the preparation and properties of notable compounds such as potassium dichromate and permanganate, as well as the significance of lanthanoid and actinoid contractions.
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4.5.3
Oxidation States
This section discusses the concept of oxidation states, particularly the phenomenon of disproportionation, which occurs when an element in a specific oxidation state becomes less stable and either gains or loses electrons to enter two different oxidation states.
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Term: Transition Metals
Definition: Elements that have partially filled d orbitals and exhibit properties such as variable oxidation states and catalytic activity.
Term: Lanthanoid Contraction
Definition: The gradual decrease in ionic and atomic sizes from lanthanum to lutetium due to ineffective shielding of the nuclear charge by 4f electrons.
Term: Electronic Configuration
Definition: The distribution of electrons in an atom's orbitals, which determines the element's chemical properties and reactivity.