11.2.2 - Rules for Determining the Number of Significant Figures

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Understanding Non-zero Digits

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Teacher
Teacher

Good morning, class! Today, we’re going to dive into significant figures. Let’s start with non-zero digits. Does anyone know why they are important?

Student 1
Student 1

I think they show how precise a measurement is?

Teacher
Teacher

Exactly! All non-zero digits are significant. For example, in 45.87 grams, how many significant figures do we see?

Student 2
Student 2

Four significant figures!

Teacher
Teacher

Right! Remember this with the acronym 'N' for Non-zero. Every non-zero digit stands proud and tells its significance.

Student 3
Student 3

So, what about zeros? Are they always significant?

Teacher
Teacher

Great question! Not all zeros are significant, and that's what we'll discuss next.

The Role of Zeros

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Teacher
Teacher

Now, let’s talk about zeros. What about zeros between significant digits, like in 2005 mL?

Student 4
Student 4

Those zeros are significant too, right?

Teacher
Teacher

"Absolutely! We call those 'sandwich zeros.'

Applying Significant Figures in Calculations

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0:00
Teacher
Teacher

Now, how do these rules apply when we do calculations? Let’s start with addition and subtraction.

Student 1
Student 1

We round to the least number of decimal places, right?

Teacher
Teacher

Correct! For example, if I add 12.11 and 0.3, how should I round the answer?

Student 2
Student 2

To one decimal place, so it would be 12.4.

Teacher
Teacher

Perfect! Now, what about multiplication and division?

Student 3
Student 3

We round to the least number of significant figures.

Teacher
Teacher

Exactly! If I multiply 2.50 by 1.2, what do you get?

Student 4
Student 4

3.0 since we only have two significant figures in 1.2.

Teacher
Teacher

Correct! Remember, your calculations shouldn’t imply more precision than your measurements. Let's recap this significant figure application.

Introduction & Overview

Read a summary of the section's main ideas. Choose from Basic, Medium, or Detailed.

Quick Overview

This section outlines the rules for determining the number of significant figures in a measurement, emphasizing their importance in conveying precision.

Standard

The section discusses key principles for identifying significant figures in various contexts, including non-zero digits, zeros between significant digits, leading zeros, and trailing zeros. It also highlights how to apply these rules in calculating the results of measurements accurately.

Detailed

Rules for Determining the Number of Significant Figures

Significant figures are fundamental in conveying the precision of a measurement and ensuring accurate communication of scientific data. In this section, we will outline the systematic rules for identifying significant figures and apply these principles in calculations.

Key Rules for Determining Significant Figures:

  1. Non-zero digits: Any digit that is not zero is considered significant. For example, in the measurement 45.87 g, all digits are significant, resulting in four significant figures.
  2. Zeros between non-zero digits: Zeros that appear between significant digits are significant. For instance, 2005 mL contains four significant figures, and 10.08 s also contains four significant figures.
  3. Leading zeros: Zeros that precede all non-zero digits are not significant; they merely serve as placeholders. In the measurement 0.0025 kg, only the digits 2 and 5 are significant, leading to just two significant figures. Similarly, in 0.010 g, there are also two significant figures.
  4. Trailing zeros: These refer to zeros at the end of a number and are significant only if the number contains a decimal point. For example, 2.500 g has four significant figures, while 2500 g could have two, three, or four significant figures; therefore, it is recommended to express ambiguous values in scientific notation to avoid uncertainty.

In the latter part of this section, we address how to apply the rules of significant figures in calculations:

  1. For Addition and Subtraction: The number of decimal places in the result should match the measurement with the fewest decimal places.
  2. For Multiplication and Division: The result should reflect the number of significant figures of the measurement with the fewest significant figures.
  3. Exact Numbers: These have an infinite number of significant figures and do not limit the figures of calculated results.

By understanding and applying these rules systematically, students can communicate measurements accurately and maintain the scientific rigor demanded in measurements.

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Non-zero Digits

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  1. Non-zero digits: Any digit that is not zero is significant.

β—‹ Example: 45.87 g has 4 significant figures.

Detailed Explanation

This rule states that all digits from 1 to 9 count as significant figures. These are the foundation of expressing the precision of a measurement. For instance, in the number 45.87 g, every digit (4, 5, 8, and 7) counts towards the significant figures, totaling four significant figures.

Examples & Analogies

Think of these digits as the building blocks of a measurement. Just like every brick is essential to create a sturdy wall, every non-zero digit contributes to the overall precision of our measured value.

Sandwich Zeros

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  1. Zeros between non-zero digits (Sandwich Zeros): Zeros located between two significant non-zero digits are significant.

β—‹ Example: 2005 mL has 4 significant figures. 10.08 s has 4 significant figures.

Detailed Explanation

This rule highlights that if a zero is found between two non-zero digits, it is also considered significant. For example, in the number 2005, the zeros between the 2 and 5 are significant because they help specify the precision of the measurement. Thus, 2005 has 4 significant figures.

Examples & Analogies

Imagine sandwich layers. Just as the filling between two slices of bread is critical to having a complete sandwich, the zeros between the non-zero digits play a crucial role in conveying the exact value in measurements.

Leading Zeros

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  1. Leading zeros: Zeros that come before non-zero digits (at the beginning of a number) are not significant. They are merely placeholders to indicate the position of the decimal point.

β—‹ Example: 0.0025 kg has 2 significant figures. 0.010 g has 2 significant figures.

Detailed Explanation

Leading zeros are any zeros that appear before the first non-zero digit. These do not count as significant figures because they do not affect the precision of the measurement; they simply allow us to place the decimal point correctly. For instance, in 0.0025, the zeros do not affect the meaning of the measurement, so it has only 2 significant figures.

Examples & Analogies

Think of leading zeros like the '0's that often appear before your telephone number or your street address - they don't change the actual value of the number itself, but they help in correctly placing it in context.

Trailing Zeros with Decimal Point

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  1. Trailing zeros (at the end of a number):

β—‹ With a decimal point: Trailing zeros are significant if the number contains a decimal point. This indicates that these zeros were measured or are exact.

β–  Example: 2.500 g has 4 significant figures. 120.0 L has 4 significant figures.

Detailed Explanation

Trailing zeros are the zeros that come after the last non-zero digit. If a number has a decimal point, these trailing zeros are considered significant because they indicate that the measurement is precise and that the zeros were actually part of the measurement. For instance, 2.500 g has four significant figures because of the three digits and the trailing zero.

Examples & Analogies

Think of trailing zeros like the frosting on a cake; they enhance the appearance (or precision) of your measurement, showing that you are confident every part - including the zeros - was accounted for during measurement.

Trailing Zeros without Decimal Point

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β—‹ Without a decimal point: Trailing zeros in a number without a decimal point are often ambiguous. It's unclear whether they are significant or merely placeholders.

β–  Example: 2500 g could have 2, 3, or 4 significant figures. To avoid ambiguity, use scientific notation.

Detailed Explanation

When trailing zeros appear without a decimal point, it's difficult to determine if they should count as significant figures. The measurement 2500 g could be interpreted as having 2, 3, or 4 significant figures, which can lead to confusion in understanding the precision of the measurement. To clarify, it's better to use scientific notation to specify exactly how many figures are significant.

Examples & Analogies

Picture a scenario where you're counting cash. If you say you have $2500, it's unclear if you have $2500 exactly or if you might have $2500.50. Just like using specific bills to clarify your exact amount, scientific notation clears up ambiguity in measurements.

Type mcq

Options: 3, 4, 5
Correct Answer: 5
Explanation: All non-zero digits and zeros between them are significant. Trailing zeros after a decimal point are also significant.
Hint: Systematically apply all the rules for significant figures.
Question: True or False: When multiplying 1.2 cm by 3.456 cm, the answer should have three significant figures.

Type: boolean
Options: True, False
Correct Answer: False
Explanation: The factor with the fewest significant figures is 1.2 (2 sig figs). Therefore, the answer should be rounded to 2 significant figures.
Hint: Remember the rule for multiplication regarding significant figures.
Question: Which of the following numbers correctly represents 500 kg with three significant figures?

Type: mcq
Options: 5Γ—10
2
Β kg, 5.0Γ—10
2
Β kg, 5.00Γ—10
2
Β kg
Correct Answer: 5.00Γ—10
2
Β kg
Explanation: In scientific notation, all digits in the mantissa are significant. To show three significant figures, the mantissa must have three digits.
Hint: Pay close attention to how scientific notation communicates precision.
Challenge Problems
Problem: A graduated cylinder has markings every 1 mL. You measure a volume of 25.5 mL. When considering the absolute uncertainty, how many significant figures should be used to report this measurement?

Solution: 25.5Β±0.5Β mL (3 significant figures).
Hint: For analog instruments, estimate to one-half of the smallest scale division. This estimated digit is significant.
Problem: You perform a dilution, taking 10.00 mL of a stock solution and diluting it to a final volume of 100.00 mL. If the stock solution's concentration is 0.150 M, calculate the diluted concentration, ensuring your final answer reflects the correct number of significant figures.

Solution: 0.0150 M.
Hint: Consider how each volume measurement (which are exact numbers in this context and do not limit sig figs) and the initial concentration contribute to the significant figures of the final answer. Remember the dilution formula: M1V1=M2V2