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Today's lecture will highlight how equilibrium is relevant in our everyday lives. Can anyone think of an example of equilibrium?
How about carbonated drinks? The gas is dissolved but can come out.
Exactly! Carbonated drinks illustrate chemical equilibrium. When you open a bottle, the COβ comes out of solution, but in a sealed bottle, there's an equilibrium between dissolved COβ and gas. Remember the acronym 'CAP' for Carbonation, Air pressure, and Partial pressureβthese factors play a role in maintaining that equilibrium.
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What about the example of saturated salt solutionsβdoes anyone know how it illustrates equilibrium?
In such a solution, salt and water are mixed, and the salt doesnβt keep dissolving once it's saturated.
Correct! Thereβs equilibrium between undissolved salt and the ions in the solution. Try to remember 'SALT'βSaturation, Active ions, Liquid, and Transition to help recall this example. What can happen if more salt is added?
It wonβt dissolve anymore; it stays as solid.
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Let's move on to water vapor in a closed container. Can someone explain this example of equilibrium?
When water is inside, some of it evaporates but then some condenses back into the water.
Exactly! This back-and-forth continues until equilibrium is reached, where the rates of evaporation and condensation are equal. To remember this, think of 'EVC'βEvaporation, Vapor, Condensation. It shows how dynamic equilibrium can be!
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Let's summarize the examples of equilibrium we discussed. Who can remind me of the first one?
Carbonated drinks!
And then the saturated salt solution!
Finally, the water vapor with evaporation and condensation.
Great job! Remember, equilibrium is not just a concept; it's something we experience every day!
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Section 7.6 demonstrates how equilibrium is present in everyday life through examples such as carbonated drinks, saturated salt solutions, and the evaporation and condensation of water vapor in closed containers.
In this section, we explore various examples of equilibrium as experienced in daily life. Equilibrium describes a state in which opposing processes occur at equal rates, resulting in no net change. One prime example is found in carbonated beverages. In these drinks, carbon dioxide (COβ) gas is dissolved in the liquid, maintaining an equilibrium between COβ gas above the liquid and the dissolved COβ within it. Another example is a saturated salt solution, where solid salt is in a state of equilibrium with its dissolved ions. Lastly, the relationship between evaporation and condensation in water vapor within a closed container exemplifies equilibrium; as water evaporates, it is balanced by the condensation of water vapor back into liquid. Each of these scenarios illustrates how the principles of equilibrium apply prominently in physical and chemical contexts, enriching our understanding of everyday phenomena.
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β Carbonated drinks: COβ gas in equilibrium with dissolved COβ.
In carbonated drinks, carbon dioxide gas (COβ) is dissolved in the liquid. When the drink is sealed, the gas is in equilibrium with the dissolved gas. This means that some COβ molecules are escaping from the liquid into the gas space, while others are dissolving back into the liquid at the same rate. This dynamic balance keeps the drink fizzy until the bottle is opened, allowing gas to escape and the equilibrium to shift.
Think of a fizzy drink like a sealed bottle of soda. When you shake the bottle, the pressure builds up, preventing COβ from escaping. Once you open it, the pressure drops suddenly, and the gas begins to escape, leading to the loss of fizz. This is similar to how equilibrium works in systems β when conditions change, the balance is disrupted.
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β Saturated salt solution: Salt β Dissolved ions.
In a saturated salt solution, there is a dynamic equilibrium between solid salt (like table salt) and the sodium (Na+) and chloride (Cl-) ions dissolved in water. At equilibrium, the rate at which salt dissolves into ions is equal to the rate at which the ions combine to form solid salt. This means that no additional salt will dissolve, even if more salt is added, until some liquid evaporates.
Imagine stirring salt into a glass of water. At first, the salt dissolves, but after a while, you can only dissolve so much. If you keep adding salt and reach a point where the bottom of the glass has undissolved salt, thatβs your saturated solution. This situation demonstrates how equilibrium works: processes are happening in balance, even if you can see solid salt in the bottom.
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β Water vapor in a closed container: Evaporation β Condensation.
In a closed container with water, there are two processes happening: evaporation, where water molecules turn into vapor, and condensation, where vapor turns back into water. At equilibrium, the rate of evaporation equals the rate of condensation. This means the amount of water vapor and liquid water remains constant over time, even though both processes are ongoing.
Think about a jar with a lid filled with water. After some time, the inside of the lid may become cloudy due to condensation. Meanwhile, water is constantly evaporating into vapor. At some point, the amount of evaporated water in the air balances with how much is condensing back into the liquid. Itβs like a dance where both partners are moving, but the number of dancers stays the same!
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Key Concepts
Equilibrium: The state when opposing processes occur at equal rates.
Saturated Solutions: Solutions where no more solute can be dissolved.
Evaporation and Condensation: Processes that reach equilibrium in closed systems.
See how the concepts apply in real-world scenarios to understand their practical implications.
Carbonated drinks maintain equilibrium between COβ gas and dissolved COβ.
A saturated salt solution exemplifies equilibrium of undissolved solid salt and dissolved ions.
In a closed container of water, the rates of evaporation and condensation illustrate equilibrium.
Use mnemonics, acronyms, or visual cues to help remember key information more easily.
In carbonated drinks, bubbles don't run; dissolved COβ means equilibrium fun!
Imagine a magical jar of salty water. When itβs full, no more salt can join the partyβitβs saturated!
Remember EVC: Evaporation, Vapor, Condensation to recall the water cycle in a closed container.
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Review the Definitions for terms.
Term: Equilibrium
Definition:
A state in which opposing processes occur at the same rate.
Term: Saturated Solution
Definition:
A solution that contains the maximum amount of solute that can dissolve at a given temperature.
Term: Evaporation
Definition:
The process by which liquid water changes to vapor.
Term: Condensation
Definition:
The process through which vapor turns back into liquid.