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Let's start with hydrophobicity. Can anyone tell me what hydrophobic means?
I think it means 'water-fearing'?
Exactly! Compounds that are hydrophobic do not mix well with water. Can you think of an example?
Like oils?
Yes, oils are a great example! They don't dissolve in water because they are hydrophobic. Now, why do you think long-chain hydrocarbons are less soluble in water compared to shorter ones?
Because they have more carbon and hydrogen, right? They might be more hydrophobic?
That's correct! More carbons mean more hydrophobic characteristics. Remember, the more carbon atoms an organic compound has, the less soluble it is in water. Let's remember that with the acronym 'C-H-O' standing for 'Carbon, Hydrophobic, Less Soluble'!
Now let's compare organic and inorganic compounds. Which do you think has higher solubility in water?
I think inorganic compounds do. They dissolve better in water.
Right! Inorganic ions and salts are generally very soluble in water because they can ionize. Can anyone give me a reason why that is?
Maybe because they can interact with water molecules better?
Exactly! They dissociate into ions which are polar, making them highly soluble. Let's use the memory aid 'I-O' for 'Inorganics are Optimal' when remembering that inorganic compounds are usually more soluble.
What are the two main types of solids we talk about when analyzing water quality?
Dissolved solids and suspended solids?
Correct! Total Dissolved Solids or TDS includes everything dissolved, while Total Suspended Solids or TSS includes things that are floating but not dissolving. Why do you think we care about these two measurements in water quality?
Because they can affect how safe the water is to drink?
Exactly! High levels of suspended solids can indicate contamination. Let's use the mnemonic 'D-S for Drink Safe' to remember that we assess these solids to ensure the water is safe to drink.
We discussed the overall hydrophobicity of organic compounds, but what about those that have functional groups, like -OH or -COOH? How do you think those behave?
I think they would be more soluble, right? Because of polarity?
Absolutely! Those functional groups can enhance solubility because they can interact with water molecules. Let's remember 'F-G for Functional Groups' as a memory aid that compounds with these groups tend to be more soluble.
Finally, can anyone tell me what other contaminants we might be concerned about in water, aside from dissolved or suspended solids?
Microorganisms like bacteria?
Exactly! Microbial contaminants can be a major health risk. It's essential to remember proper filtration methods to remove these microbes before water is deemed safe to drink. Let's use 'M-C for Microbial Control' to remember the importance of addressing this aspect in water safety.
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The section delves into the concepts of hydrophobicity and solubility of organic compounds, presenting how organic compounds generally have lower solubility in water compared to inorganic compounds. It highlights the role of functional groups in influencing solubility and the definitions surrounding dissolved and suspended solids in water.
In this section, we explore the relationship between hydrophobicity and the solubility of organic compounds in water. Hydrophobicity is a term used to describe the tendency of a compound to repel water. Many organic compounds, particularly those with long carbon chains (alkanes) or without polar functional groups, exhibit hydrophobic characteristics and therefore have low solubility in water. In contrast, inorganic compounds, particularly salts and ions, typically have much higher solubility in water due to their ability to dissociate into ions and interact with water molecules.
This section also explains the concept of screening for water quality, which provides a rapid assessment of water's suitability for drinking based on visible signs like color, turbidity, smell, and taste. These initial observations prompt further analysis of the water, which can classify the types of pollutants present. Thus, understanding hydrophobicity helps in predicting the solubility of various chemicals found in water, which is vital for water quality assessments.
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So, there is this term which is called as Hydrophobicity, we will come come back to this term later, the context of this is not with the in the in solubilities, it’s something else, so it is relative, okay, Anyway, so organic components also can be present, it’s finite solubility, but this is larger. For this one, solubility is very large, much much larger than that of organic compound, okay.
Hydrophobicity refers to the tendency of a compound to repel water. In simple terms, hydrophobic substances do not mix well with water. This is important because it affects how substances behave in water. Organic compounds are generally less soluble in water than inorganic compounds. For instance, oils and fats (which are organic compounds) do not dissolve in water because they are hydrophobic. The solubility refers to how well a substance can dissolve in another substance, and in this case, organic compounds have lower solubility in water compared to inorganic ones.
Think of oil and water in a salad dressing. When you mix oil (organic) with water (inorganic), the oil floats on top because it's hydrophobic. This is why, when you make a salad dressing, you often shake it up to temporarily mix them, but they will eventually separate again, highlighting the differences in their solubility.
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So, there is one thing that you have to understand straightaway that many of these organic compounds also have solubility, all of them have solubilities, it’s it’s just low, it’s just water doesn’t like water, but it can be present in water, okay.
While organic compounds are primarily hydrophobic and have low solubility in water, it's crucial to understand that they still can dissolve to some extent. This means that even though water does not mix well with most organic compounds, small amounts can still be present in the water. This is often seen with substances like sugar or alcohol, which can dissolve in water despite being organic.
Imagine trying to mix sand (hydrophobic) in water. You might not be able to dissolve the sand completely, but if you add a little bit of salt (an inorganic compound), it dissolves easily. This illustrates how some organic compounds can be present in water, but generally not in large amounts.
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If you look at the data of solubility versus the number of carbons, it is usually decreasing with the number of carbons as you, but if you have a group here, say I have a compound with an OH group or a COOH group or an NH or some such thing or even chlorine sometimes, some 2 of these have higher solubilities in water than something that does not have ‘H’, but still these compounds are not in comparison to inorganic salts, the solubility is very low.
The solubility of organic compounds often decreases as the length of their carbon chain increases. This means that larger organic molecules are generally less soluble in water. However, certain functional groups like -OH (hydroxyl) or -COOH (carboxyl) can increase solubility because they can interact more favorably with water. Despite this, even with these groups, organic compounds usually don't reach the high solubility that many inorganic salts do.
Think of glucose, a simple sugar which has several -OH groups. Glucose dissolves well in water, unlike long-chain fatty acids that may have many carbon atoms but lack such functional groups. It’s similar to how adding sugar to tea makes it sweet but isn’t comparable to adding salt, which dissolves completely and enhances the taste in a different way.
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So what about suspended solids? What do you think are there in suspended solids? What is the classification what what type of material can be suspended in water, which means it is not dissolving, it’s an insoluble precipitate compound that doesn’t dissolve in water or it can be suspended.
Suspended solids refer to particles that are not dissolved in water and remain dispersed within it. These can include various materials such as dirt, silt, and other particulate matter. Unlike dissolved substances that become part of the water's liquid phase, suspended solids do not dissolve, and their presence can affect water quality by making it appear cloudy or turbid.
Imagine a glass of muddy water. The mud represents suspended solids, which gives the water its cloudy appearance. You can think of suspended solids like the crumbs that float on the surface of a settled bowl of soup – they are there but have not dissolved and will remain suspended unless filtered out.
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Key Concepts
Hydrophobicity: Describes how organic compounds repel water, affecting solubility.
Organic Compounds vs Inorganic Compounds: Inorganic compounds generally exhibit higher solubility in water.
Total Dissolved Solids (TDS): Measures both organic and inorganic dissolved materials.
Total Suspended Solids (TSS): Measures particles suspended in water that do not dissolve.
Functional Groups: Certain groups can increase the solubility of organic compounds in water.
See how the concepts apply in real-world scenarios to understand their practical implications.
The hydrocarbon octadecane (C18H38) is an organic compound known for its low solubility in water due to its long carbon chain.
Sodium chloride (NaCl), an inorganic salt, is highly soluble in water as it dissociates into sodium and chloride ions.
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Hydrophobic oils that float and sway, refuse to mix with water's play.
Imagine a party where water is dancing with friends. Oils come in, but they don't join; they stay to themselves, separate from the fun.
C-H-O: Carbon means Hydrophobic, hence Low solubility!
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Review the Definitions for terms.
Term: Hydrophobicity
Definition:
The tendency of a compound to repel water; 'water-fearing'.
Term: Organic Compounds
Definition:
Compounds primarily made of carbon, often not soluble in water.
Term: Inorganic Compounds
Definition:
Compounds that usually have high solubility in water, such as salts and ions.
Term: Total Dissolved Solids (TDS)
Definition:
The total concentration of dissolved substances in water, both organic and inorganic.
Term: Total Suspended Solids (TSS)
Definition:
The total concentration of suspended particles in water that do not dissolve.