CBSE Grade 12 Chemistry Part 2 | 6. Haloalkanes and Haloarenes by Pavan | Learn Smarter
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6. Haloalkanes and Haloarenes

6. Haloalkanes and Haloarenes

Haloalkanes and haloarenes are classified based on the number of halogen atoms present, exhibiting distinct chemical properties and reactivity. Their synthesis is primarily achieved through various methods such as nucleophilic substitution and electrophilic aromatic substitution, with significant applications across industries. Understanding their behavior and reactivity is crucial, particularly in terms of environmental impact and organic synthesis.

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  1. 6
    Haloalkanes And Haloarenes

    This section covers the classification, nomenclature, preparation, and...

  2. 6.1
    Classification Of Haloalkanes And Haloarenes

    This section discusses the classification, nomenclature, and various...

  3. 6.1.1
    On The Basis Of Number Of Halogen Atoms

    This section discusses the classification of haloalkanes and haloarenes...

  4. 6.1.2
    Compounds Containing Sp3 C−xbond(X=f,cl,br,i)

    This section focuses on haloalkanes and haloarenes, detailing their...

  5. 6.1.3
    Compounds Containing Sp² C—x Bond

    This section discusses vinylic halides and aryl halides, which involve...

  6. 6.2
    Nomenclature Of Haloalkanes And Haloarenes

    This section covers the nomenclature, classification, preparation methods,...

  7. 6.3
    Nature Of Carbon-Halogen Bond

    The section discusses the characteristics and significance of carbon-halogen...

  8. 6.4
    Methods Of Preparation Of Haloalkanes

    This section discusses the various methods for preparing haloalkanes and...

  9. 6.4.1
    From Alcohols

    This section discusses methods for synthesizing haloalkanes from alcohols,...

  10. 6.4.2
    From Hydrocarbons

    This section discusses the preparation and classification of haloalkanes and...

  11. 6.4.3
    Halogen Exchange Reactions

    This section discusses halogen exchange reactions, particularly the...

  12. 6.5
    Preparation Of Haloarenes

    This section explores the preparation methods, properties, and significance...

  13. 6.6
    Physical Properties Of Haloalkanes

    This section details the physical properties of haloalkanes, focusing on...

  14. 6.7
    Chemical Reactions Of Haloalkanes

    This section discusses the chemical reactions of haloalkanes, focusing on...

  15. 6.7.1
    Reactions Of Haloalkanes

    This section covers the reactions of haloalkanes, focusing on nucleophilic...

  16. 6.7.2
    Reactions Of Haloarenes

    This section discusses the reactions of haloarenes, focusing on their less...

  17. 6.8
    Polyhalogen Compounds

    This section covers polyhalogen compounds, their nomenclature,...

  18. 6.9

    This section covers the classification, properties, and reactions of...

  19. 6.10

    This section elaborates on the classification, nomenclature, preparation,...

What we have learnt

  • Haloalkanes and haloarenes can be classified based on the number of halogen atoms as mono, di, or polyhalogen compounds.
  • The carbon-halogen bond in alkyl halides is polarized, causing reactivity with nucleophiles.
  • Various preparation methods exist for alkyl and aryl halides, including reactions with alcohols and via electrophilic substitution.

Key Concepts

-- Nucleophilic substitution
A reaction mechanism where a nucleophile replaces a leaving group in a haloalkane.
-- Elimination reaction
A process in which a b-hydrogen and a halogen are removed from adjacent carbon atoms, forming an alkene.
-- Ambident nucleophiles
Nucleophiles that can react through two different atoms, each providing a site for nucleophilic attack.
-- Chirality
A property of a molecule that has a non-superimposable mirror image, often leading to optical activity.

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