CBSE Grade 12 Chemistry Part 2 | 9. Amines by Pavan | Learn Smarter
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9. Amines

9. Amines

Amines are derivatives of ammonia formed by replacing hydrogen atoms with alkyl or aryl groups, classified as primary, secondary, and tertiary. Their structure influences their physical and chemical properties, including basicity, boiling point, and solubility. Additionally, diazonium salts, obtained from aromatic amines, play a crucial role in synthesizing various organic compounds through substitution reactions.

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  1. 9

    Amines are derivatives of ammonia formed by replacing one or more hydrogen...

  2. 9.1
    Structure Of Amine

    Amines are organic compounds derived from ammonia by replacing hydrogen...

  3. 9.2
    Classification

    This section provides an overview of amines, their classification into...

  4. 9.3
    Nomenclature

    This section covers the classification, nomenclature, and preparation...

  5. 9.4
    Preparation Of Amines

    This section covers the various methods used to prepare amines, including...

  6. 9.4.1
    Reduction Of Nitro Compounds

    This section discusses the reduction of nitro compounds to amines, detailing...

  7. 9.4.2
    Ammonolysis Of Alkyl Halides

    This section discusses the mechanism and significance of the ammonolysis...

  8. 9.4.3
    Reduction Of Nitriles

    This section covers the reduction of nitriles to primary amines, detailing...

  9. 9.4.4
    Reduction Of Amides

    This section discusses the reduction of amides to form amines and the...

  10. 9.4.5
    Gabriel Phthalimide Synthesis

    The Gabriel phthalimide synthesis is a method for preparing primary amines...

  11. 9.4.6
    Hoffmann Bromamide Degradation Reaction

    The Hoffmann bromamide degradation reaction is a method for synthesizing...

  12. 9.5
    Physical Properties

    This section discusses the physical properties of amines, including their...

  13. 9.6
    Chemical Reactions

    This section describes the reactivity of amines, including their basic...

  14. 9.6.1
    Basic Character Of Amines

    Amines are basic in nature, reacting with acids to form salts and...

  15. 9.6.2

    Alkylation involves the reaction of amines with alkyl halides to form higher...

  16. 9.6.3

    This section outlines the characteristics, classifications, and synthesis of...

  17. 9.6.4
    Carbylamine Reaction

    The carbylamine reaction describes the formation of isocyanides from primary...

  18. 9.6.5
    Reaction With Nitrous Acid

    Amines react with nitrous acid in distinct ways, leading to the formation of...

  19. 9.6.6
    Reaction With Arylsulphonyl Chloride

    The section discusses the reactions of amines, particularly primary and...

  20. 9.6.7
    Electrophilic Substitution

    This section covers the process of electrophilic substitution reactions...

  21. 9
    Ii. Diamonium Salts

    This section discusses amines as derivatives of ammonia and their...

  22. 9.7
    Methos Of Preparation Of Diazonium Salts

    Diazonium salts are prepared from primary aromatic amines through a process...

  23. 9.8
    Physical Properties Of Diazonium Salts

    This section discusses the classification, structure, and physical...

  24. 9.9
    Chemical Reactions Of Diazonium Salts

    This section covers the chemical reactions involving diazonium salts,...

  25. 9.9.1
    Reactions Involving Displacement Of Nitrogen

    This section discusses the displacement reactions involving diazonium salts,...

  26. 9.9.2
    Reactions Involving Retention Of Diazo Group Coupling Reactions

    This section discusses diazonium salts and their reactions, with a focus on...

  27. 9.10
    Importance Of Diazonium Salts In Synthesis Of Aromatic Compounds

    Diazonium salts play a crucial role as intermediates in the synthesis of...

What we have learnt

  • Amines are classified based on the number of hydrogen atoms replaced.
  • The boiling point of amines is influenced by hydrogen bonding.
  • Diazonium salts are important intermediates in organic synthesis.

Key Concepts

-- Amines
Organic compounds derived from ammonia by substituting one or more hydrogen atoms with alkyl or aryl groups.
-- Diazonium Salts
Compounds containing a diazonium group (-N2+), formed by the reaction of nitrous acid with primary aromatic amines, used extensively in aromatic substitution reactions.
-- Basicity of Amines
Amines are basic due to the presence of an unshared electron pair on nitrogen, which can accept protons.

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