Capillary Rise
Capillary rise is a phenomenon where a liquid, such as water, rises in a narrow tube against the force of gravity due to the interactions between the liquid molecules and the tube's surface. This occurs primarily due to adhesive forces between the liquid and the walls of the tube, coupled with the cohesive forces within the liquid itself. When the liquid wets the surface of the tube (for example, water in a glass tube), it creates a concave meniscus where the surface tension results in a pressure difference.
In a circular capillary tube of radius a
, the pressure difference across the liquid-air interface due to the curvature of the surface is given by the equation:

where:
- P_i
: pressure inside the tube,
- P_0
: atmospheric pressure outside the tube,
- S
: surface tension of the liquid,
- θ
: contact angle between the liquid and tube.
The height of the liquid rise, also known as capillary height h
, is related to the pressure difference by the equation:

Therefore, we can conclude that:

The smaller the radius of the tube, the higher the liquid will rise due to greater curvature, which induces a larger pressure difference. In contrast, for a liquid that does not wet the surface, such as mercury in a glass tube, the meniscus is convex, and the liquid will descend rather than rise. This section emphasizes the significance of these phenomena in understanding fluid dynamics and interactions at interfaces.