In this section, we delve into the pivotal observations made by Heinrich Hertz in 1887, during his experiments on electromagnetic waves. Hertz discovered that when high voltage sparks occurred across a detector loop, the presence of ultraviolet light significantly enhanced the sparks’ intensity. This indicated that light shining on a metal surface helped in the escape of free electrons, illustrating the phenomenon of photoelectric emission. Hertz's work provided crucial insight into how light energy can be absorbed by electrons, allowing them to overcome attractive forces within the metal. His results served as an essential foundation for later theories of light and its dual nature as both a wave and a particle, thus helping to establish the concept of photoelectric effect.