Chapter 8: Acids and Base

The chapter explores the definitions, strengths, and quantitative measures of acids and bases, including their roles in chemical processes and biological systems. It introduces the Brønsted-Lowry and Lewis theories, explains the behavior of strong and weak acids and bases, and highlights the significance of buffer solutions. Additionally, the chapter covers titrations and calculates the dynamics involved in polyprotic acids.

You've not yet enrolled in this course. Please enroll for free to listen to audio lessons, classroom podcasts and take mock test.

Sections

  • 7

    Acids And Bases

    This section provides an overview of acids and bases, covering their definitions, strengths, quantitative measures, buffer solutions, and acid-base titrations.

  • 7.1

    Defining Acids And Bases: Brønsted-Lowry And Lewis Theories

    This section discusses the definitions of acids and bases according to Brønsted-Lowry and Lewis theories, highlighting their key characteristics and the concept of conjugate acid-base pairs.

  • 7.1.1

    The Brønsted-Lowry Theory

    The Brønsted-Lowry theory defines acids as proton donors and bases as proton acceptors, focusing on the transfer of protons in acid-base reactions.

  • 7.1.2

    The Lewis Theory

    The Lewis theory expands the definition of acids and bases beyond proton transfer to include electron pair acceptance and donation.

  • 7.2

    Strength Of Acids And Bases: Strong Vs. Weak

    This section explains the key differences between strong and weak acids and bases, focusing on their dissociation in aqueous solutions.

  • 7.2.1

    Strong Acids

    Strong acids are substances that completely dissociate in aqueous solution, releasing protons and significantly affecting pH.

  • 7.2.2

    Weak Acids

    Weak acids are defined as acids that partially dissociate in solution, with an equilibrium established between the undissociated acid and its ions.

  • 7.2.3

    Strong Bases

    Strong bases are substances that fully dissociate in aqueous solutions to produce hydroxide ions, playing a crucial role in acid-base chemistry.

  • 7.2.4

    Weak Bases

    Weak bases partially dissociate in aqueous solutions, producing hydroxide ions significantly less than their initial concentrations.

  • 7.2.5

    Relationship Between Ka , Kb , And Kw For Conjugate Pairs

    The relationship between the acid dissociation constant (Ka), base dissociation constant (Kb), and the ion product of water (Kw) is fundamental in understanding proton transfer in conjugate acid-base pairs.

  • 7.3

    Quantitative Measures: Ph, Poh, And K_w

    This section covers the quantitative measures of acidity and alkalinity, specifically pH, pOH, and the ion product of water (K_w).

  • 7.3.1

    The Ion Product Of Water (K_w)

    This section explores the ion product of water, K_w, and its significance in determining the acid-base characteristics of aqueous solutions.

  • 7.3.2

    The Ph Scale

    The pH scale is a logarithmic measure of hydrogen ion concentration, allowing for easy assessment of acidity or alkalinity in solutions.

  • 7.3.3

    The Poh Scale

    The pOH scale is a measure of hydroxide ion concentration in a solution, similar to the pH scale for hydrogen ions, and is crucial in understanding acidic and basic solutions.

  • 7.3.4

    Relationship Between Ph, Poh, And K_w

    This section focuses on the quantitative measures of acidity and basicity, detailing the relationship between pH, pOH, and the ion product of water (K_w).

  • 7.3.5

    Calculations Involving Ph

    This section explores calculations related to pH, focusing on strong and weak acids and bases, and the concepts of pH, pOH, and their relationships.

  • 7.4

    Buffer Solutions: Resisting Ph Change

    Buffer solutions are crucial systems that resist changes in pH when small amounts of acid or base are added.

  • 7.4.1

    Composition Of Buffer Solutions

    Buffer solutions are crucial in maintaining a stable pH, composed of a weak acid and its conjugate base or a weak base and its conjugate acid.

  • 7.4.2

    How Buffers Work

    Buffer solutions resist changes in pH when small amounts of acid or base are added, crucial for maintaining stable environments in various chemical and biological contexts.

  • 7.4.3

    Buffer Capacity

    Buffer capacity refers to the ability of a buffer solution to resist changes in pH upon the addition of acids or bases.

  • 7.4.4

    Henderson-Hasselbalch Equation

    The Henderson-Hasselbalch equation provides a method to calculate the pH of buffer solutions using concentrations of weak acids and their conjugate bases.

  • 7.5

    Hl: Acid-Base Titration Curves And Indicators

    Titration curves visually represent the change in pH during the titration process and aid in understanding the equivalence point and selecting suitable indicators.

  • 7.5.1

    Key Features Of A Titration Curve

    Titration curves visually represent the change in pH as a titrant is added to an analyte, highlighting important features such as the buffer region, equivalence point, and endpoint.

  • 7.5.2

    Acid-Base Indicators

    Acid-base indicators are substances that exhibit different colors in their acidic and basic forms, allowing for the identification of pH changes during titrations.

  • 7.5.3

    Choosing The Right Indicator

    This section explains how to select appropriate acid-base indicators based on their pKa values and the characteristics of the titration curve.

  • 7.6

    Hl: Calculations Involving Polyprotic Acids

    This section explains polyprotic acids, emphasizing their ability to donate multiple protons stepwise and the corresponding calculations for their pH.

  • 7.6.1

    Key Characteristics Of Polyprotic Acid Dissociation

    This section outlines the key characteristics of polyprotic acids, including their stepwise dissociation and the significance of their successive acid dissociation constants (Ka).

  • 7.6.2

    Calculating The Ph Of Polyprotic Acids

    This section discusses the calculations involved in determining the pH of polyprotic acids, their unique dissociation steps, and how to approach problems involving these acids.

  • 7.6.3

    Titration Curves Of Polyprotic Acids

    This section discusses the unique characteristics of titration curves for polyprotic acids, highlighting the presence of multiple equivalence points and buffer regions.

Class Notes

Memorization

What we have learnt

  • Acids and bases can be defi...
  • The strength of acids and b...
  • Buffer solutions maintain s...

Final Test

Revision Tests

Chapter FAQs