3.9.1 - Types of Deleterious Substances
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Introduction to Deleterious Substances
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Today we’re going to discuss deleterious substances in aggregates, which can negatively impact our concrete. What do you think 'deleterious' means in this context?
Does it mean harmful or bad things in the aggregates?
Exactly! A good way to remember this is through the acronym 'DANGERS' - Detrimental, Altering, Noxious, Grading, Enhancing, Reducing Strength. These substances weaken the concrete itself. Can anyone name some examples?
Is clay one of them? I remember it weakens the bond.
Correct, clay is a significant deleterious material. Let’s summarize: clay and silt, for instance, can increase water demand and weaken the bond with cement.
Effects of Deleterious Materials
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Now that we know what deleterious materials are, let's talk about how they affect concrete. What effect do you think organic impurities have?
I think they might slow down how fast the concrete sets up?
Right! They can actually retard setting and hardening. Remember the phrase 'organic is slow'? That might help you recall its impact.
What about salts? I heard they can cause problems too.
Yes! Salts can lead to corrosion of steel and efflorescence. Think of 'salties corrode!'. It’s crucial to monitor these materials to maintain concrete durability.
Understanding Permissible Limits
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Let’s shift focus to permissible limits for these troubling materials. Who knows what the limit is for clay lumps?
Is it less than 1%?
Perfect! Just like '1 is number one, keep clay lumps under'. Let's continue – what about soft particles?
Oh! That should be less than 3%. I remember because three is a few.
Excellent memory! Monitoring these limits helps ensure concrete can withstand the test of time.
Introduction & Overview
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Quick Overview
Standard
This section identifies various deleterious materials such as clay, organic impurities, and reactants that can negatively impact concrete. It also specifies the allowable limits for these materials in aggregates according to industry standards, emphasizing the importance of quality control in concrete production.
Detailed
Types of Deleterious Substances
Deleterious materials present in aggregates can adversely affect the performance and durability of concrete. Their presence can weaken the bond between cement and aggregate, increase water demand, and compromise the overall structural integrity of concrete mixes.
Key Deleterious Materials
- Clay and Silt: These materials weaken the bond with cement and increase the water demand of concrete, which can lead to a decrease in its durability.
- Organic Impurities: Such impurities can retard the setting and hardening of cement, resulting in delays in the construction process.
- Soft Fragments: These reduce the strength of concrete, impacting its load-bearing capacity.
- Salts (Chlorides/Sulfates): These can lead to corrosion of embedded steel and efflorescence on the surface of concrete.
- Coal and Lignite: The presence of these materials can cause discoloration and weaken the overall durability of concrete.
- Alkali-Reactive Particles: These can cause expansion and cracking in concrete over time, leading to structural issues.
Permissible Limits According to IS: 383
- Clay Lumps: Less than 1%
- Soft Particles: Less than 3%
- Organic Impurities: Should pass a color test with NaOH solution, indicating very minimal presence.
This section emphasizes the significance of monitoring and controlling the quality of aggregates to ensure lasting performance and safety in concrete structures.
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Clay and Silt
Chapter 1 of 7
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Chapter Content
- Clay and silt: Weakens bond with cement, increases water demand.
Detailed Explanation
Clay and silt are small particles that can mix with aggregates. When these materials are present, they can interfere with how well the cement binds to the aggregates. This weak bond can cause the concrete structure to become less strong over time, and since clay and silt absorb water, they can also increase the overall water requirement in the concrete mix.
Examples & Analogies
Imagine trying to mix sand into a pile of mud. The mud (representing clay and silt) doesn’t allow the sand (the aggregates) to blend well, resulting in a weaker mixture. This is similar to how clay and silt disrupt the bond between the aggregates and cement in concrete.
Organic Impurities
Chapter 2 of 7
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Chapter Content
- Organic impurities: Retards setting and hardening.
Detailed Explanation
Organic impurities, such as plant matter or decaying substances in aggregates, can slow down the chemical process that allows cement to harden. This means that the concrete takes longer to set, which can be problematic especially in construction timelines. If these impurities aren’t removed, the integrity of the concrete can be compromised, affecting its durability.
Examples & Analogies
Think of making a cake. If you add rotten fruit to the batter, it can spoil the whole cake. Similarly, organic impurities in concrete can delay its hardening process and ultimately weaken the final product.
Soft Fragments
Chapter 3 of 7
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Chapter Content
- Soft fragments: Reduces strength.
Detailed Explanation
Soft fragments in aggregates are weak materials that do not provide sufficient structural support. When soft fragments are present, the overall strength of the concrete is lowered because they can break down easily under pressure. This can lead to structural failures in concrete works, especially those that need to bear heavy loads.
Examples & Analogies
Imagine trying to build a tower using marshmallows instead of bricks. As soon as you put weight on it, the marshmallows squish and collapse, failing to support the structure. That’s what happens with soft fragments in concrete.
Salts (Chlorides/Sulfates)
Chapter 4 of 7
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Chapter Content
- Salts (chlorides/sulfates): Corrosion of steel, efflorescence.
Detailed Explanation
Salts like chlorides and sulfates can cause significant damage to concrete. They can lead to the corrosion of any steel reinforcements within the concrete, which weakens the structural integrity. Additionally, these salts can cause efflorescence, which is a white powdery substance on the surface of the concrete, indicating ongoing chemical reactions that can deteriorate the concrete over time.
Examples & Analogies
Think about how salt can cause damage to roads and vehicles in winter. Just as road salt can corrode a car's metal body, chlorides from salts can corrode the steel inside concrete, leading to major problems down the line.
Coal and Lignite
Chapter 5 of 7
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Chapter Content
- Coal and lignite: Discoloration and poor durability.
Detailed Explanation
Coal and lignite are types of coal that, when present in aggregates, can cause discoloration of concrete and negatively affect its overall durability. These materials may not bond well with cement and can lead to patches and stains on the surface, making the finished concrete look unprofessional and weak.
Examples & Analogies
Imagine painting a wall with different shades of paint. If you add coal dust, it would not only change the nice color you aimed for but might also weaken the wall material. Similarly, coal and lignite affect the appearance and strength of concrete.
Alkali-Reactive Particles
Chapter 6 of 7
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Chapter Content
- Alkali-reactive particles: Causes expansion and cracking.
Detailed Explanation
Alkali-reactive particles in aggregates, particularly those containing reactive silica, can react with hydroxides in cement when moisture is present. This reaction produces a gel that expands over time, leading to cracking and deterioration in the concrete. The presence of these particles must be carefully managed to prevent long-term damage to concrete structures.
Examples & Analogies
Think of a sponge immersed in water. As it absorbs moisture, it expands. Similarly, alkali-reactive particles cause concrete to swell, leading to cracks, much like if the sponge pushed against other objects and caused damage.
Permissible Limits
Chapter 7 of 7
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Chapter Content
- Permissible Limits (IS: 383):
- Clay lumps: <1%
- Soft particles: <3%
- Organic impurities: Should pass color test with NaOH solution.
Detailed Explanation
The Indian Standard (IS: 383) sets specific permissible limits for various deleterious substances to ensure quality in concrete mixes. Clay lumps should not exceed 1%, soft particles should be less than 3%, and any organic impurities must pass a color test when mixed with a sodium hydroxide solution. Adherence to these limits helps maintain the integrity and performance of concrete.
Examples & Analogies
Consider following safety regulations when driving a car. Just like there are speed limits and other rules to keep you safe on the road, these permissible limits ensure that the concrete used in construction remains strong and durable, safeguarding structures.
Key Concepts
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Deleterious materials can significantly weaken concrete.
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Clay and silt increase water demand and reduce strength.
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Organic impurities can retard setting times.
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Salts can corrode steel reinforcement.
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Permissible limits ensure quality control in aggregate use.
Examples & Applications
Clay in aggregates increases the water required for a mix by 20% at times, affecting the water-cement ratio.
Presence of organic impurities can delay concrete setting for hours, leading to project delays.
Salts in aggregates have been linked to premature concrete spalling due to efflorescence.
Memory Aids
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Rhymes
Clay is gray, it takes away; water rushes needed each day.
Stories
A builder learned that clay made his mortar weak, and that salty roads caused terrible streaks. He mixed wisely, avoiding the wrong things, and strengthened the concrete for good functioning.
Memory Tools
Remember C.O.C.S. - Clay, Organic, Coal, Salts.
Acronyms
DEAL - Deleterious effects include
Increased water demand
Enhanced setting time issues
Loss of strength.
Flash Cards
Glossary
- Deleterious Materials
Substances that negatively affect the performance and durability of concrete.
- Clay
Fine-grained soil that weakens the bond with cement and increases water demand.
- Organic Impurities
Substances derived from living organisms that can retard the setting and hardening of concrete.
- Salts
Substances such as chlorides and sulfates that can lead to corrosion and efflorescence.
- Permissible Limits
The maximum allowable percentage of deleterious materials in concrete aggregates according to industry standards.
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