Types of Deleterious Substances - 3.9.1 | 3. Aggregates for Concrete | Concrete Technology
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3.9.1 - Types of Deleterious Substances

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Interactive Audio Lesson

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Introduction to Deleterious Substances

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0:00
Teacher
Teacher

Today we’re going to discuss deleterious substances in aggregates, which can negatively impact our concrete. What do you think 'deleterious' means in this context?

Student 1
Student 1

Does it mean harmful or bad things in the aggregates?

Teacher
Teacher

Exactly! A good way to remember this is through the acronym 'DANGERS' - Detrimental, Altering, Noxious, Grading, Enhancing, Reducing Strength. These substances weaken the concrete itself. Can anyone name some examples?

Student 2
Student 2

Is clay one of them? I remember it weakens the bond.

Teacher
Teacher

Correct, clay is a significant deleterious material. Let’s summarize: clay and silt, for instance, can increase water demand and weaken the bond with cement.

Effects of Deleterious Materials

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0:00
Teacher
Teacher

Now that we know what deleterious materials are, let's talk about how they affect concrete. What effect do you think organic impurities have?

Student 3
Student 3

I think they might slow down how fast the concrete sets up?

Teacher
Teacher

Right! They can actually retard setting and hardening. Remember the phrase 'organic is slow'? That might help you recall its impact.

Student 4
Student 4

What about salts? I heard they can cause problems too.

Teacher
Teacher

Yes! Salts can lead to corrosion of steel and efflorescence. Think of 'salties corrode!'. It’s crucial to monitor these materials to maintain concrete durability.

Understanding Permissible Limits

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0:00
Teacher
Teacher

Let’s shift focus to permissible limits for these troubling materials. Who knows what the limit is for clay lumps?

Student 2
Student 2

Is it less than 1%?

Teacher
Teacher

Perfect! Just like '1 is number one, keep clay lumps under'. Let's continue – what about soft particles?

Student 1
Student 1

Oh! That should be less than 3%. I remember because three is a few.

Teacher
Teacher

Excellent memory! Monitoring these limits helps ensure concrete can withstand the test of time.

Introduction & Overview

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Quick Overview

Deleterious substances in aggregates can significantly hinder concrete performance by affecting strength, setting time, and durability.

Standard

This section identifies various deleterious materials such as clay, organic impurities, and reactants that can negatively impact concrete. It also specifies the allowable limits for these materials in aggregates according to industry standards, emphasizing the importance of quality control in concrete production.

Detailed

Types of Deleterious Substances

Deleterious materials present in aggregates can adversely affect the performance and durability of concrete. Their presence can weaken the bond between cement and aggregate, increase water demand, and compromise the overall structural integrity of concrete mixes.

Key Deleterious Materials

  1. Clay and Silt: These materials weaken the bond with cement and increase the water demand of concrete, which can lead to a decrease in its durability.
  2. Organic Impurities: Such impurities can retard the setting and hardening of cement, resulting in delays in the construction process.
  3. Soft Fragments: These reduce the strength of concrete, impacting its load-bearing capacity.
  4. Salts (Chlorides/Sulfates): These can lead to corrosion of embedded steel and efflorescence on the surface of concrete.
  5. Coal and Lignite: The presence of these materials can cause discoloration and weaken the overall durability of concrete.
  6. Alkali-Reactive Particles: These can cause expansion and cracking in concrete over time, leading to structural issues.

Permissible Limits According to IS: 383

  • Clay Lumps: Less than 1%
  • Soft Particles: Less than 3%
  • Organic Impurities: Should pass a color test with NaOH solution, indicating very minimal presence.

This section emphasizes the significance of monitoring and controlling the quality of aggregates to ensure lasting performance and safety in concrete structures.

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Audio Book

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Clay and Silt

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  • Clay and silt: Weakens bond with cement, increases water demand.

Detailed Explanation

Clay and silt are small particles that can mix with aggregates. When these materials are present, they can interfere with how well the cement binds to the aggregates. This weak bond can cause the concrete structure to become less strong over time, and since clay and silt absorb water, they can also increase the overall water requirement in the concrete mix.

Examples & Analogies

Imagine trying to mix sand into a pile of mud. The mud (representing clay and silt) doesn’t allow the sand (the aggregates) to blend well, resulting in a weaker mixture. This is similar to how clay and silt disrupt the bond between the aggregates and cement in concrete.

Organic Impurities

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  • Organic impurities: Retards setting and hardening.

Detailed Explanation

Organic impurities, such as plant matter or decaying substances in aggregates, can slow down the chemical process that allows cement to harden. This means that the concrete takes longer to set, which can be problematic especially in construction timelines. If these impurities aren’t removed, the integrity of the concrete can be compromised, affecting its durability.

Examples & Analogies

Think of making a cake. If you add rotten fruit to the batter, it can spoil the whole cake. Similarly, organic impurities in concrete can delay its hardening process and ultimately weaken the final product.

Soft Fragments

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  • Soft fragments: Reduces strength.

Detailed Explanation

Soft fragments in aggregates are weak materials that do not provide sufficient structural support. When soft fragments are present, the overall strength of the concrete is lowered because they can break down easily under pressure. This can lead to structural failures in concrete works, especially those that need to bear heavy loads.

Examples & Analogies

Imagine trying to build a tower using marshmallows instead of bricks. As soon as you put weight on it, the marshmallows squish and collapse, failing to support the structure. That’s what happens with soft fragments in concrete.

Salts (Chlorides/Sulfates)

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  • Salts (chlorides/sulfates): Corrosion of steel, efflorescence.

Detailed Explanation

Salts like chlorides and sulfates can cause significant damage to concrete. They can lead to the corrosion of any steel reinforcements within the concrete, which weakens the structural integrity. Additionally, these salts can cause efflorescence, which is a white powdery substance on the surface of the concrete, indicating ongoing chemical reactions that can deteriorate the concrete over time.

Examples & Analogies

Think about how salt can cause damage to roads and vehicles in winter. Just as road salt can corrode a car's metal body, chlorides from salts can corrode the steel inside concrete, leading to major problems down the line.

Coal and Lignite

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  • Coal and lignite: Discoloration and poor durability.

Detailed Explanation

Coal and lignite are types of coal that, when present in aggregates, can cause discoloration of concrete and negatively affect its overall durability. These materials may not bond well with cement and can lead to patches and stains on the surface, making the finished concrete look unprofessional and weak.

Examples & Analogies

Imagine painting a wall with different shades of paint. If you add coal dust, it would not only change the nice color you aimed for but might also weaken the wall material. Similarly, coal and lignite affect the appearance and strength of concrete.

Alkali-Reactive Particles

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  • Alkali-reactive particles: Causes expansion and cracking.

Detailed Explanation

Alkali-reactive particles in aggregates, particularly those containing reactive silica, can react with hydroxides in cement when moisture is present. This reaction produces a gel that expands over time, leading to cracking and deterioration in the concrete. The presence of these particles must be carefully managed to prevent long-term damage to concrete structures.

Examples & Analogies

Think of a sponge immersed in water. As it absorbs moisture, it expands. Similarly, alkali-reactive particles cause concrete to swell, leading to cracks, much like if the sponge pushed against other objects and caused damage.

Permissible Limits

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  • Permissible Limits (IS: 383):
  • Clay lumps: <1%
  • Soft particles: <3%
  • Organic impurities: Should pass color test with NaOH solution.

Detailed Explanation

The Indian Standard (IS: 383) sets specific permissible limits for various deleterious substances to ensure quality in concrete mixes. Clay lumps should not exceed 1%, soft particles should be less than 3%, and any organic impurities must pass a color test when mixed with a sodium hydroxide solution. Adherence to these limits helps maintain the integrity and performance of concrete.

Examples & Analogies

Consider following safety regulations when driving a car. Just like there are speed limits and other rules to keep you safe on the road, these permissible limits ensure that the concrete used in construction remains strong and durable, safeguarding structures.

Definitions & Key Concepts

Learn essential terms and foundational ideas that form the basis of the topic.

Key Concepts

  • Deleterious materials can significantly weaken concrete.

  • Clay and silt increase water demand and reduce strength.

  • Organic impurities can retard setting times.

  • Salts can corrode steel reinforcement.

  • Permissible limits ensure quality control in aggregate use.

Examples & Real-Life Applications

See how the concepts apply in real-world scenarios to understand their practical implications.

Examples

  • Clay in aggregates increases the water required for a mix by 20% at times, affecting the water-cement ratio.

  • Presence of organic impurities can delay concrete setting for hours, leading to project delays.

  • Salts in aggregates have been linked to premature concrete spalling due to efflorescence.

Memory Aids

Use mnemonics, acronyms, or visual cues to help remember key information more easily.

🎵 Rhymes Time

  • Clay is gray, it takes away; water rushes needed each day.

📖 Fascinating Stories

  • A builder learned that clay made his mortar weak, and that salty roads caused terrible streaks. He mixed wisely, avoiding the wrong things, and strengthened the concrete for good functioning.

🧠 Other Memory Gems

  • Remember C.O.C.S. - Clay, Organic, Coal, Salts.

🎯 Super Acronyms

DEAL - Deleterious effects include

  • Increased water demand
  • Enhanced setting time issues
  • Loss of strength.

Flash Cards

Review key concepts with flashcards.

Glossary of Terms

Review the Definitions for terms.

  • Term: Deleterious Materials

    Definition:

    Substances that negatively affect the performance and durability of concrete.

  • Term: Clay

    Definition:

    Fine-grained soil that weakens the bond with cement and increases water demand.

  • Term: Organic Impurities

    Definition:

    Substances derived from living organisms that can retard the setting and hardening of concrete.

  • Term: Salts

    Definition:

    Substances such as chlorides and sulfates that can lead to corrosion and efflorescence.

  • Term: Permissible Limits

    Definition:

    The maximum allowable percentage of deleterious materials in concrete aggregates according to industry standards.