In this section, the concepts of atomic number (Z) and mass number (A) are introduced. Atomic number (Z) is defined as the total number of protons in an atomic nucleus, which also equals the number of electrons in a neutral atom. For example, hydrogen has an atomic number of 1 because it has 1 proton. Mass number (A), on the other hand, is the total count of protons and neutrons (nucleons) in an atom's nucleus; hence, it can be expressed as A = Z + n (number of neutrons). The section further explains that isobars are atoms with the same mass number but different atomic numbers, while isotopes are atoms with the same atomic number but different masses due to differing numbers of neutrons. This foundational knowledge aids in understanding the variety of isotopes and their applications in fields such as radiochemistry and nuclear energy. Overall, these concepts are crucial for identifying elements on the periodic table and understanding their behavior in chemical reactions.